catena-Poly[[tris(4-fluorobenzyl)tin(IV)]-μ-2-[(piperidin-1-yl)carbothioylsulfanyl]acetato-κ2 O:O′]
نویسندگان
چکیده
Adjacent units of the title polymeric complex, [Sn(C(7)H(6)F)(3)(C(8)H(12)NO(2)S(2))], are bridged by the carboxyl-ate ion into a helical chain running along the b axis. The Sn(IV) atom shows a distorted trans-C(3)SnO(2) trigonal-bipyramidal coordination and is displaced by 0.113 (2) Å out of the C(3)Sn girdle in the direction of the covalently bonded O atom. The ring is disordered of two positions with an occupancy of 0.631 (4) for the major occupied site.
منابع مشابه
catena-Poly[[tris(4-fluorobenzyl)tin(IV)]{μ-[(N,N-diisopropylcarbamothioyl)sulfanyl]acetato-κ2 O:O′}]
In the title compound, [Sn(C(7)H(6)F)(3)(C(9)H(16)NO(2)S(2))](n), the Sn atom is coordinated in a slightly distorted, trans-C(3)SnO(2) trigonal-bipyramidal environment. Symmetry-related Sn atoms are bridged by diisopropyl-dithio-carbamoylacetato ligands, forming a one-dimensional polymer along [001].
متن کاملcatena-Poly[[(acetato-κO)[4-(1H-pyrazol-3-yl)pyridine-κN 1]zinc]-μ-acetato-κ2 O:O′]
In the title compound, [Zn(CH(3)CO(2))(2)(C(8)H(7)N(3))](n), the Zn(II) atom is coordinated by one N atom from a 4-(1H-pyrazol-3-yl)pyridine ligand and three O atoms from two bridging and one terminal acetate ligands, forming a distorted tetra-hedral geometry. The bridging acetate ligands link the Zn atoms into a chain along [001]. N-H⋯O hydrogen bonds and π-π inter-actions between the pyridine...
متن کاملcatena-Poly[[triphenyltin(IV)]-μ-2-[(3,5-di-tert-butyl-4-hydroxybenzyl)sulfanyl]acetato-κ2 O:O′]
The title compound, [Sn(C(6)H(5))(3)(C(17)H(25)O(3)S)](n), comprises two symmetry-independent five-coordinated triphenyl-tin mol-ecules which are linked by carboxyl-ate bridges into a polymeric chain. The Sn(IV) atom is in a distorted trans-C(3)SnO(2) trigonal-bipyramidal geometry. The presence of two bulky tert-butyl groups on the benzene ring prevents any hydrogen-bonding inter-actions involv...
متن کاملcatena-Poly[[manganese(II)-tris(μ-betaine-κ2 O:O′)] tetrabromidomanganate(IV)
The title compound, [Mn(C(5)H(11)NO(2))(3)]·MnBr(4), contains polymeric cationic chains of distorted MnO(6) octa-hedra and bridging betaine mol-ecules, running parallel to the a axis. There are two distinct Mn(2+) cations in the chain, both with site symmetry . Distorted [MnBr(4)](2-) tetra-hedra occupy the spaces between the chains.
متن کاملcatena-Poly[diethyl(2-hydroxyethyl)ammonium [[tetra-μ-acetato-κ8 O:O′-dicuprate(II)(Cu—Cu)]-μ-acetato-κ2 O:O′] dichloromethane solvate]
The title compound, {(C(6)H(16)NO)[Cu(2)(CH(3)COO)(5)]·CH(2)Cl(2)}(n), consists of acetate-bridged Cu(2)(CH(3)COO)(4) units that are connected via another acetate anion at each terminus to form infinite anionic [{Cu(2)(CH(3)COO)(4)}(CH(3)COO)](n) chains along [100]. The connecting acetate is hydrogen bonded to the dieth-yl(2-hydroxy-ethyl)ammonium cation, and the dichloro-methane solvent mol-ec...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 66 شماره
صفحات -
تاریخ انتشار 2010